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HomeMy WebLinkAbout1989 Circulation and Water Quality of Mats Mats Bayr r I. A Report Prepared for McConnell /Burke 11000 NE 33rd Place Suite 101 Bellevue, WA 98004 CIRCULATION AND WATER QUALITY OF MATS MATS BAY HLA/Harper -Owes Job No. 19436,001.09 by Thomas J.Smayda Aquatic Scientist Martin E. Harper, PA., Ph.D.. Consulting Principal Engineer HLA /Harper -Owes 1325 Fourth Avenue, Suite 2110 Seattle, Washington 98101 206/622 -0812 December 5, 1989 \lJ � s •� t •a� �a An oceanographic survey was conducted in Mats Mats Bay, Washington during the summer of 1989 to evaluate existing environmental conditions. This monitoring effort focused on water circulation and flushing as well as water quality. Key water quality parameters identified included nutrients, which promote algal growth, and fecal bacteria, which may contaminate shellfish. The flushing and circulation characteristics of the bay were assessed because of the great influence they exert on the distribution and concentration of these constituents. Developed data was contrasted with existing Class AA water quality criteria and with water characteristics from other embayments. Mats Mats Bay is uniquely configured with a narrow channel through which all tidal exchange occurs. Sampling conducted within the channelized inflow and outflow has permitted mass balance evaluation of constituents entering and leaving the bay. Sampling has targeted periods of low tidal exchange in an effort to identify worst case conditions. The presented description of these results includes an estimate of the pollutant assimilative capacity of Mats Mats Bay. STUDY AREA Mats Mats Bay is a Class AA (WAC 173 -201) tidal basin located on the northeast portion of Washington State's Olympic Peninsula, two miles due north of Port Ludlow (Figure 1). The bay is a small, sheltered basin isolated from the Admiralty Inlet portion of Puget Sound by a narrow, doglegged channel (Figure 2). Rolling hills rise to elevations of 100 to 600 feet and surround the bay. The hilly terrain, small fetch and angled channel combine to reduce wind and wave action within Mats Mats Bay. The' catchment area is approximately 2.4 square miles and annual rainfall on the order of 24 inches. Runoff from this catchment enters the bay via three small creeks. The largest of these enters the northwest corner of Mats Mats Bay and the other two enter the southwest portion. Approximately 85% of the catchment is vegetated, 10% is the bay surface, and 5% has been cleared for small farms, residences, roadways, and the Mats Mats quarry. Predominant tree species in the catchment are Douglas -fir, western red cedar, red alder, western hemlock, and big leaf maple. Common shrubs include rhododendron, salal, salmonberry, and huckleberry. Swordfern dominates the herbaceous layer. Soils in the catchment (USDA, 1975) are dominated by Alderwood gravelly sandy loams with 0 -15% slopes. The soil is approximately 20 -40 inches thick, and rests on a cemented layer. V r 1 N 41 �l 5 4 122 9W 48' 44' 40' 36• t Figure 7 MATS MATS BAY LOCATION MAP 3 •• Si 9� MATS MATS BAY PORT 6, LUDLOW '� S •_ �• •ilk• HOOD CANAL.:';::;:; <. 21 BRIDGE •mot 122 9W 48' 44' 40' 36• t Figure 7 MATS MATS BAY LOCATION MAP 3 t t Figure 2 BATHYMETRIC MAP AND SAMPLING LOCATIONS. 4 N O 500 1000 • 18 2 12 SCALE FEET .. jAA . � • • • . 1 • . ' <- 15 _ • ��` '= SAMPLING STATIONS • 10 SEAWATER ' 3 • ..� • ''' 1 CREEK ❑ • ,b , • , Q SHELLFISH 12 . 2• 3 :••: • SOUNDINGS IN FEET Figure 2 BATHYMETRIC MAP AND SAMPLING LOCATIONS. 4 { The soil is moderately well drained and the permeability above the cemented layer is moderately rapid. Alderwood soils are located west and north of the bay and directly abut shorelines on the northern edge of the channel and the eastern portion of the bay. v Cassolary sandy loams with 0 to 15% slopes are located immediately adjacent to the southern and western portions of the bay. This is well drained soil, at least 5 feet deep and permeability is moderately slow. Kitsap silt loams are not immediately adjacent to the bay, but, are exposed along much of the bed of the creek which drains to the northwest corner of the bay. These 5 foot deep soils have 0 -30% slopes, are moderately well drained and permeability is characterized as very slow. The remaining soil in the Mats Mats Bay catchment is an Olete very gravelly silt loam which lies in the vicinity of the quarry on Basalt Point, east of the channel. This 20 -30 inch soil is sloped between 0 -30%. Permeability is moderate and the soil well drained. Runoff from all of the soils in the watershed is slow to medium and the erosion hazard' is slight to moderate. The ability for the loamy Alderwood and Kitsap soils to assimilate pollutants from roadways, agricultural runoff, or septic drain fields is deemed to be moderate. However, during the wet season, soils above the cemented layer may become saturated and not function so well (USDA, 1975). The Cassolary soils, on which a number of the perimeter homes have been constructed, may provide better treatment if suitable travel distance through unsaturated soils exists. The Olete soils of Basalt Point are shallow and relatively permeable which minimizes the ability of the soil column to adsorb pollutants. Land immediately surrounding Mats Mats Bay is predominated by single family residences. Approximately 35 houses are located within 200 feet of its shores. There are also two near -shore hobby farms. A quarry pit which crushes 300 tons of rock per year is located on Basalt Point. This operation includes a fiberglass blanket screen designed to trap suspended material which would otherwise enter Mats Mats Bay. A herring bait facility operates on the eastern edge of the bay. Floating net pens are used for holding live herring from 10 to 14 days (Rubida, 1989). Approximately 2.7 million herring are held and sold by this operation annually. A commercial oyster bed has been located at the north end of Mats Mats Bay. R The bay is a well protected anchorage and during Summer 1989, approximately 20 boats were moored there during midweek. Approximately 3 live - aboards were observed anchored midweek; more than 20 live - aboards may gather during peak use weekends. METHODS Sample Stations. Seawater samples (Figure 2) were collected from a background station (Sta. 1) located in Admiralty Inlet, due west of the Mats Mats channel opening and about 1 mile offshore. A station within the channel (Sta. 2) was sampled during both rising and falling tides on each sample date. Two stations were located within the bay (Sta. 3 and 4). Three creek stations were sampled. Oyster samples were collected primarily from a single station, however, on one date were also collected near the creek entrances. Sample Dates. Water quality samples were collected once per month between July and October. "Worst case" conditions were targeted by the collection of bay samples during the last half of ebb tide and during minimal tidal ranges. Tidal ranges varied from 0.6 to 13.3 feet over the study period (Figure 3A). Tidal ranges sampled ranged from 1.65 feet to 2.64 feet and averaged 2.33 ± 0.46 feet. The frequency distribution of tidal range (Figure 4A) indicates that small tidal amplitude is fairly frequent despite the large spread in tidal ranges. Sampled tides represent the 11% smallest tides. A small tide is generally followed by one with great range (Figure 3A), thus even when small tides occur, the average daily tidal range is large. A daily average is meaningful because many marine processes, such a phytoplankton growth, are strongly influenced by events which occur on a daily time scale. The daily average exchange based on tidal prism during sample dates was 49.0 ± 3.4 million cubic feet, also within the 11th percentile over the study period (Figure 4B). Drogue studies of water motion were conducted once during a minimal tidal range and once during an average range. Together with the drogue studies, water quality samples were collected from Mats Mats channel in support of mass balance calculations. Sample Acauisition. Depth composite samples were collected from each station with a gang of Niskin bottles. Surface water was collected at the background station (Sta. 1) from depths of 1 m, 3 m and 5 m, equal volumes blended in a large bucket and then subsampled into the necessary bottles. Deep water was similarly collected from 10 m, 20 m, and 40 m. Composite samples were collected from the channel inflow and outflow points (Sta. 2I, 20) and from the northern portion of Mau Mats Bay (Sta. 4) from depths of 1 m and I m above the bottom. Three prewashed and prelabeled nalgene bottles, a 250 ml and two 1 L were filled from each composite. Samples were stored on ice in a cooler for transport back to the laboratory. Upon return to the lab, the 250 ml sample from each composite was acidified with four drops of concentrated H2SO4 and deep frozen for subsequent total phosphorous analysis. One 1 L sample was whole for fecal coliform, TKN, NH4 -N and total residual chlorine and 100 ml and 25 ml alequoits were filtered for NO3 + NO2 and Chl p analyses, respectively. In addition, at each station, separate casts of the sample collection bottles were made to collect water for dissolved oxygen (DO) determination. DO samples were immediately and directly drawn into 300 ml BOD bottles (displacing 3 volumes 'of water). A YSI i Model 57 DO meter was used in the field, and 10 percent of the samples were (, duplicated and preserved in the field with manganese sulfate and alkaline iodide solutions for subsequent Winkler Titration V (Strickland and Parsons, 1972). R 1 6. i TIDAL HEIGHT (FEET) A. 10 s s 4 2 O -2 -4 WATER EXCHANGE (MILLION CUBIC FEET /DAY) 100 B. 90 6o 70 60 6o 40 JULY AUGUST SEPTEMBER OCTOBER Figure 3 TIDAL RANGE (A) AND DAILY WATER EXCHANGE (B). ARROWS INDICATE SAMPLING DATES. ~- ' - |� FREQUENCY (number) FREQUENCY (percent) IRA 0- 1710 TIDAL RANGE (feet) FREQUENCY (number) FREQUENCY (percent) am 40 45 50 55 60 65 70 75 80 85 WATER EXCHANGE (million cubic feet/day) ~ | ` _ | . m Figure 4 FREQUENCY DISTRIBUTION OF TIDAL RANGE (A) AND DAILY WATER EXCHANGE (B). 8 (' Basin Manning. Bottom contours of Mats Mats Bay were determined by taking 7 transects across the bay. A boat was driven at a uniform velocity along each transect line and over 100 readings were taken with a depth sounder at equal time increments. A weighted line was used to calibrate these readings. Approximately 40 additional depth measurements were also made with the line to quantify depths between transects. Depth measurements were corrected for tidal height at the time of measurement and adjusted to use MHW as a reference datum. Isobaths were contoured by linear interpolation at three foot increments. Near shore isobaths were confirmed with aerial photographs taken at known tidal height. Areas between isobaths were determined using a planimeter. Volumes for each 3 foot stratum were calculated by the "average -ends" method. Water Exchanae Calculations. Water exchange has been calculated by three methods, but all based upon the notion of tidal prism and using Mats Mats basin morphometry as determined in this study. The first, tidal prism exchange, is calculated based upon the assumption that bay water is exchanged for the incoming ocean water without mixing. Tidal prism is the volume of water contained in the intertidal zone. Tidal prism exchange is expressed in percent as the ratio of the tidal prism volume to the mean bay volume. The second estimate of water exchange assumes that water which enters on the rising tide is completely mixed with bay water before discharge with the falling tide. . By this process, each tidal cycle mixes with resident water and gradually dilutes it, but can never replace all of the original water. This relationship is conveniently expressed as water residence half -life in terms of tidal cycles: Tide cycles to replace half of the mean bay volume - (0.693)(avg. tidal range) (avg. Vol.) Provided that the assumptions for this calculation are met, 1 half -life discharges 50% of the average bay volume, 2 half -lives displace 75%, 3 displace 87.5% and so on. The third estimate is based on tidal excursion. By this method, water is considered to move by plug flow. The rising tide enters uniformly up the central axis of the bay and the falling tide discharges as a plug. The tidal excursion estimates are helpful in that the potential for poor flushing in remote areas of the bay can be assessed. Drogue Studies. Near - surface water movements were followed with drogues made from party balloons filled with fresh water (Nixon et al., 1980). The drogues floated with less than 1/8 inch projecting above water level and with drafts of 6 to 8 inches. Groups of 5 drogues, each group a different color, were deployed at 4 locations within Mats Mats Bay on the outgoing tide and a group of 20 balloons was released at a single point in mid- channel near the entrance to the bay during the rising tide. Drogue locations were noted approximately hourly by approaching each balloon in a boat and triangulation with a compass to on -shore landmarks. Balloon movement was large during outgoing tides and it was necessary to periodically capture and rerelease each balloon group at the original starting positions. Wind speed and direction were estimated throughout the study. Two complete tidal cycles, one during a period of minimal tidal exchange and one during an average tidal prism, were so assayed. 0 Field Data: Temoerature. Salinity. Secchi depth. The vertical distribution of t! temperature and salinity was determined at each station with a YSI model 33 S -C -T meter. The probe was lowered through the water column and temperature and salinity were recorded at 1 m intervals from the surface to 12 m. Secchi depth was measured on the shady side of the boat. Nutrients: NO. + NQ2, NH4. TKN. TP. Nutrients were determined by an independent testing lab. Samples for NO3 + NO2 - N were filtered through prewashed 0.45 um membrane filters and those for NH4 - N and TKN were analyzed on unfiltered fractions. NO3 + NO2 - N were analyzed by an automated cadmium reduction method, NH4 - N by an automated phenate method and TKN by a micro- Kjeldahl method with phenate finish (APHA 1985). Total phosphorus was assessed on unfiltered seawater samples following persulfate digestion by the ascorbic acid /molybdenum blue method (APHA 1985). Samples were acidified to pH I with H2SO4 and deep frozen until analysis. Fecal Coliform. Fecal Coliform was determined by the multiple tube fermentation technique by an independent testing laboratory and results were presented in terms of Most Probable Number (MPN) (APHA 1985). This technique is chosen to provide continuity with past sampling efforts. Chlorophyll a. Samples were filtered for Chl a following vigorous shaking of the seawater samples by filtering approximately 25 ml (as needed) through 4.5 cm Gelman GF /C glass fiber filter paper and spiked with 1 ml of magnesium carbonate suspension. The magnesium carbonate suspension will be prepared by adding 1 g of finely powdered, reagent grade magnesium carbonate plus 3 g of reagent grade sodium chloride to 100 ml of distilled water in a stoppered flask. The filter paper was desiccated and deep frozen until analyses. Chl a and phaeo - pigments were analyzed by fluorometer as described by Holm- Hansen et al (1983). Air Temperature, Wind Sneed. Tide. Air temperature and wind speed was determined from instruments located at Port Ludlow Harbormaster Restaurant Lobby immediately prior to sample collection. Tide conditions for Port Ludlow were determined from a Seattle tide chart (NOAA) corrected for height by a ratio of 0.88 and corrected for time by subtracting 27 minutes to determine high tides and subtracting 18 minutes for low tides. Mats Mats Bay tides are considered to be well represented by Port Ludlow tides. Statistics, Significance was assessed with a Student's t test at a 95% confidence interval. RESULTS AND DISCUSSION Data Ouality Assurance Data quality is described by five basic points: (1) Accuracy. Data accuracy has been determined by matrix spike addition for nutrients and salinity. Results (Table 1) 1 d indicate that accuracy has ranged from 89.1% to 107.3%. EPA guidelines for RCRA facility investigations consider matrix spike recovery in the range of 75% to 125% acceptable. (2) Precision. Precision describes the repeatability of a measurement. For 10 Y r. a d � 4-1 m K cr t+ +3 43b acs oa a m 0 ..1 w m 4� z avi a, a tea .-1 crb —I m d� 41 14 43 0� w a J a a, mock. 0 +J a o mtca0 Id 4D Id a' � r. ...1 .- a r1 k t. k C Oa d 010 � � m 0 .c 1a a o E A w aI U d I a o aai a z d ►e � Ha z d Ww Ai .Ea A cc z+� d R W V a 0 A � o •� a 01' z a .r K K be H H K Nt - CDwOm cm N CID 0 t'7 t- T-4 W-1 r-i 1-1 1-1 W-1 HbtKkKk epNO -WujGD NOlrltoNN o=mtot - t- mmGoMQCD .-1 .-1 Mtootht - Go N KKKKKKK CDm"rt --44mw eP u7 t- 9-1 m 0 m P+ •-1 K K K k K K K K tp M N CV3 co m •-1 u7 wM tr- N N t- m t► W4 tz ; NCO Nc m0Nt►m er•a' V4 +0 --I d a +1 ..1 awc. -.1. -4a 4+ 0 0 0 o 9: -4 "4 .N e o .a x -•+ A 4J «, a +J A A. •--1.t 0% z 0 0A 0 a t .-1 a a o 0 0 .c .-1 k as > Ga o V a .-1 ..1 +.; 0 +A 0 ..-I -r7 0 E- 41 d o ..1 [-E .0 a 0 co i1 0 AL i' example, if a sample is reanalyzed several times and the results are very close, then a high level of precision has been achieved. The relative percent difference (RPD) between duplicate samples is a measure of precision and has been used for this study. Measured RPD (Table 1) have ranged from 0.4% to 15.7% for nutrients and salinity but were in excess of 25% for Chl 1i and for phaeophytin. EPA guidelines indicate that for data to be of good quality the RPD should be less than 20%. (3) Completeness. The available data is considered to be complete if it is sufficient to describe the environment according to plan. The data set presented here is complete enough, both in terms of numbers of stations and number of sample episodes, to assess environmental impacts of the sewage effluent discharge. (4) Representativeness. Representativeness describes how well the data reflect actual site conditions and is primarily influenced by the sampling program and analytical methodology. Mats Mau Bay samples have been collected during the summer season and during the last half of ebb tide on days with minimal tidal exchange. Thus, with respect to water flushing, worst case conditions have been targeted and the data is evaluated in that context. (5) Comparability. Data which has been collected and analyzed with standardized methods may be cross compared with confidence. Methods used were standard for oceanographic investigations. In summary, data quality is deemed wholly satisfactory for the purposes of this evaluation. Basin Morphometry Mats Mats Bay is small heart- shaped basin of about 133 acres._ Maximum and average depths at the mean tidal level are 24.7 and 9.9 feet (Table 2). Area and volume are indicated in Table 3. The deep hole is located on the eastern edge of the basin and close to the channel entrance (Figure 2). The channel is long and narrow, about 3,300 feet by 300 feet and also relatively deep, with maximum and mean depths of 15.7 and 9.5 feet respectively. The volume of Mats Mau Bay plus the channel is 57.5 million cubic feet at mean tide, of which about 77% is within the bay and 23% in the channel (Table 3). The intertidal volume is very large with respect to the basin volume (Figure 5). Approximately 65% of the basin water is discharged as the tide drops from mean high to mean low water. 12 r 4 0 eo a x A +>4 m Id U Id x a 0 m U d tU 4 U d fr d U •mot d V V U a U 0 x cA. 0 N d d E 1 1 a io i oczmC)�owgr Wo`ae i ° .°•°`°erN° i 1 1 1 1 1 NwCV� CV3 1 t 1 1 i e - CO3 - - 0 0 u- - i 1 =M-mrM •L•O 1 TaE4 1 1 I 1 1 1 1 Q L7 W 1 r-4 t- . C4 0 * 1 E 1 O-40 co N • to r4 I Dc I 1 1 I I 1 pp;; �• 1 ! Q W C9 W I C.O°G.C> co C) x �E 1 0)LAmN •N.-+ 1 � x c ; qw cla D Go x 1 I 1 I i� 4.3 4r tN 17' � d U .� W4 ...1 r.1 B ao 41 .c .N 4-3 ev a a R d 4) oc-4 --4 )aAA a0 m e a U sae adi a0i V m N, •o is d d Z 13 . , L� • 14 N N tl A ! N OI O Atla V � ! h b ! aD A !► tl tl !� a In o- m O m o b A IO C an N ton, N tl r+ ! n N Ob I! tl tl tl ! N N •� � N tl N O •+ N N tl O A A tl ! N .y O Artl wrA ntlh tl01� �•. v O O O O h'+.+ b is O Pl C'J w n C < m b ! N N A b N N N N N r1 !• O tl A O " O ! tl W ! ! I! N O •4►•! tl N !7 OA•yA � lr ! O a O O O O O O O N •r ••1 N A A �► w� n � b tl0 C N r• ti N r1 ti N 10 -1 N tl tl a a W tl A b r1 •d m 11 NC, 011,10 Nc ! n ! p a a O O O O O O .INN 1 � Pl VJI N ! W A N m O N • !� N N N N N A tl �/f A O� ! {7 01 t� Pf tl tl N • tl W ! OJ N Ol ! O O !J t. O !• N p�p r1 .-• N N O O O V. 13 l7 GOD e4 N i tl N N �o tl a b tr a tl O A . •••1 O7 N b tl ! A a ! "W . . � A I (q M O i tl ti tl tl O tl l► 14 I A Co aAO O O • C tr ! O N ": ! i 0=0 C O h > ~ ~ O O O O O O p N N p N N O i to N �9 10 N O b •!P O b O N O _ ■ 5 C ! Ol I! N N A o. V •y w s+ N tl N O A A tl N O w •ANA tlN 01!! me 40 Ol N N •+ N O O O goo a tlw a o e e Y N C K8 O O OON nNlN9 yy tl O i ! f! !0 N N H O O N Ia r1 tl O O O W 1.0 � O L W C st O tl N tl ! ! N n l7 N t tl NY N rl < N N N N Q .ai Ow C N •f A t7 �r N N an O n tl A •+ O N ! !l to r7 !If ••1 O ! ! h N N N O APO �.•AI i NtiN 5 . N O N W �•. i.�j pGp it p6 O A h am y N N b A ••4 ! N tl O N O L•1 N N tlC, !! .+ N tlOtl YO.• q O N N O O O W!•� q!N M�tl rl tl 2 e:E via " e Qr i 0 A 1 04 0 C> a .�Z E poi rs7 �M1! vi a cc as 14 r DEPTH (feet) 0 -10 —20 —30 0 x1 my DEPTH (feet) 0 —10 —20 —30 0 20 40 60 VOLUME (million cubic feet) URW 80 10 20 30 40 50 60 70 80 90 100 PERCENT VOLUME Figure 5 DEPTH VOLUME (A) AND DEPTH PERCENT VOLUME (B) CURVES. 15 t Water Exchange The average ebb tide, a 6.7 foot drop from mean high to mean low water, discharges 65% of the mean tide volume which indicates that bay water is exchanged with ocean water about 1.3 times per day. A slightly more conservative approach assumes complete mixing within the bay and indicates that the water half -life is on average 0.32 d. Thus, about 50% of the water is replaced in 0.32 d, 75% in 0.64 d and about 87.5% each 0.96 d. The 5% minimal tidal exchange is 40 to 45 million cubic feet per day (Figure 4B) and results in a water half -life of 0.55 d. Thus, even during periods of minimal flushing, considerable water exchange occurs in Mau Mats Bay. Water exchange is not simply controlled by tidal action, however. Some water washed out of the bay may reenter on the rising tide, effectively reducing the extent of flushing. On the other hand, fresh water inflow may serve to increase the volume of water flushed from the bay. Circulation within Puget Sound, for example, is strongly controlled by the volume of river inflow. Because the sound is not getting deeper, the fresh water volume must exit, and also, because the sound is not getting less salty, ocean ll water must enter to maintain the salt balance. The volume of ocean water necessary to maintain the salt balance is approximately 10 to 20 times the fresh water volume and thus density driven salt balance circulation exceeds the circulation set up by the tidal prism. For Mats Mats Bay however, the role of water reentry and that of fresh water. input are thought to be unimportant as described below. The channel from Mats Mats Bay opens to Puget Sound between Olele and Basalt Points. Effectively, the channel opening is on a promontory which extends into the Admiralty Inlet portion of Puget Sound (Figure 1). This region of Puget Sound is known to be vigorously mixed with current velocities on the order of 0.3 knots (Mofield and Larsen, 1984). Adjacent to Mats Mats Bay, prevailing currents flow northward, possibly on both ebb and flood tides, and mixing depth is generally on the order of 50 m (Harper -Owes, 1988). Thus, even in worst case conditions, water from the bay is likely swept from the channel mouth with only a small fraction available to re -enter the bay. Creek input to Mats Mats Bay was negligible during the 1989 study period. Combined flow from the three freshwater creeks was 0.32 t 0.11 cfs and represented a total inflow of about 31 million gallons. In contrast, based on data from Port Townsend, estimated evaporation from Mats Mats Bay during the same 152 day period was 20 inches, or 73 16 million gallons. Evaporation apparently exceeded inflow as confirmed by measurements t which showed that the background station in Admiralty Inlet (Sta. I) was slightly, but not statistically, less saline than Mats Mats Bay stations. Water and salt mass balance calculations can be combined to evaluate the extent of water exchange. Such estimates are extremely sensitive to salinity and now data and were not meaningful for this study. The small volume of freshwater inflow and the negligible density difference between Mats Mau Bay and Admiralty Inlet are not perceived to have a strong influence on Mats Mats Bay circulation. Therefore, tidal prism and half -life calculation are thought to represent good estimates of water exchange. The areal extent of bay flushing has been estimated with the use of a cumulative volume curve. The curve was constructed by division of the bay into sections along its central axis from the head of the bay to the mouth of the channel (Figure 6A). The water volume in each of these sections was then determined and cumulative mean high and mean low water plotted as a function of distance from the bayhead (Figure 6B). The slope of the cumulative volume lines gives information about the basin configuration along the central axis. Where the slope is steep,, the basin has a large cross sectional area due to width or depth, and where flatter, the basin has a smaller cross sectional area. Figure 6B shows that most of the volume is contained in the bay itself between 800 and 2,000 feet from the bay head as indicated by the steep slope. The channel, 2,509 to 5,855 feet from the bay head, is relatively deep but very narrow and thus contains a small volume. At mean high tide the bay contains 77% and the channel 23% of the total bay plus channel volume. The cumulative volume curve can be used to estimate the distance a parcel of water may move with a rising or falling tide. The key assumption is that tidal currents move by plug flow along the central axis rather than mixing with the resident water. The graph indicates that on the average ebb tide all water located beyond 1,500 feet from the bay head is discharged. The example tidal excursion plotted (Figure 6B) indicates that the average ebb will move a parcel of water from 1,100 feet to abut the 1,900 feet from the bay head. Thus, a conclusion is that water within the 1,537 foot boundary as drawn on Figure 6A is potentially more stagnant than water beyond. In order to more fully evaluate if water from all regions of the bay are uniformly flushed, two drogue studies were performed. To be consistent with the worst case 4 17 11�' A. ' CENTRAL AXIS 4.431'• • . .. s1�7• leas•:. • - s4o6• • • + + e t ' �' •a • DISTANCE FROM HEAD OF SAY a. `2509' . • • ,� 15378 062' 573' HEAD OF BAY ` VOLUME (million cubic feet) 80 B. 60 40 20 0 0 MHW TIDAL EXCURSION MLW 1000 2000 3000 4000 5000 6000 DISTANCE FROM THE HEAD OF THE BAY (feet) Figure 6 DISTANCE FROM HEAD OF BAY IS SEGMENTED (A) TO PRODUCE A TIDAL EXCURSION GRAPH (B) �8 flushing analysis approach of this evaluation, one drogue study was performed during a minimal tidal exchange, while the other during an average tidal cycle. Drogue paths are displayed for ebb and flood tides which occurred during periods with low and average tide range (Figures 7 -10). Predominant winds were from the north, but were very light, generally 2 to 5 knots. Surface currents moved in response to the wind and drogue movement was generally southward, into the bay, regardless of tidal direction. In some instances, balloons beached, an indicator of surface water downwelling. In other cases the balloons moved counterclockwise at the head of the bay. The picture which emerges is that the light winds which prevail during summer and fall serve to hold floating and near - surface objects within the bay despite the great tidal flushing rate. Water column stability and small scale mixing (dispersion) are additional factors which exert important influences on water exchange. Water column stability occurs when less, dense water overlies denser water. Oceanographic convention expresses density (p) in terms of sigma t (at): at =(p - l)x 103 Measured salinity and temperature have been used to calculate at from Knauss (1978). Stability (E) is an indicator of the work required to move a parcel of denser water some distance upward into a lighter layer, and is calculated as the change in potential density with depth: E =( -1 1p) x (tat /8z) x (10-3) Mats Mats Bay had stable density stratification as indicated by greater at at depth during sample occasions in July, August, and September (Table 4). Stability during this period was high, in excess of 1,000 10-8 m'1, which indicates the existence of a pycnocline, a density gradient (Fischer, 1986). Thus, during this period, the bay was not mixed from top to bottom. Complete vertical mixing was implicated during the October sampling by negative values of E. Temperature distributions indicate that the upper mixed layer was 7 to 8 feet deep. The extent of mixing within this layer is determined by the rate which drogues separated from one another. Random walk calculation (Fischer, 1988) based on the drogue data 19 a TIDE (lost) DROGUE CHECK TIMES 12 .j :. 4 ' • ' •r. 3 ',• TIME SOUNDINGS IN FEET 1 Figure 7 DROGUE STUDY EBB TIDE MINIMAL TIDAL EXCHANGE N • as 0 Soo 1 000 -° ='• ,2 _ SCALE FEET -ti.. ' • ..• •• KEY . `'� ''� . • 1O -DROGUE _• "� .• ~• RELEASE • :•• :', POINT e • •�- 1S • . ,' ` ti ';� ' •. ti� . 3TO 6 KNOTS 3 PREVAILING • . WIND 2 �lb . DROGUE CHECK TIMES 12 .j :. 4 ' • ' •r. 3 ',• TIME SOUNDINGS IN FEET 1 Figure 7 DROGUE STUDY EBB TIDE MINIMAL TIDAL EXCHANGE 0 500 1000 : ,. •' +- 2 15 C .SCALE FEET ' •';� 9 1, ; "` :•: , • = • ' KEY ' ' '' ; • • 10 'DROGUE •,� 1 RELEASE • 6 .. POINT . •� f 5 TO O KNOT C PREVAILING e WIND :•ih d� DROGUE CHECK TIMES r • ' •s 15 - 12 TIDE (test) 8 TIME • SOUNDINGS IN FEET Figure 8 DROGUE STUDY FLOOD TIDE MINIMAL TIDAL EXCHANGE TIDE (feet, a 1 r O.. 500 1000 2 15 SCALE FEET - • ; . • KEY. • (j)-DROGUE • • . � , _ RELEASE • g .;�'• .• •.a POINT ' •� 2 O TO 3 KNOTS PREVAILING • WEND 3 . DROQUE CHECK TIMES •:. •.. 15 � 12 ' O 4 4 12 10 20 24 ,• .'• TIME ; • r , • SOUNDINGS IN FEET Figure 9 DROGUE STUDY EBB TIDE AVERAGE TIDAL EXCHANGE i Y 1 Figure 10 DROGUE STUDY FLOOD TIDE AVERAGE TIDAL EXCHANGE . .f •s. 15 0 S00 1000 12 ~•'�" SCALE FEET �• • • • i• • • + M� • ...• .• KEY ' •` • •' � ' ' ;� 0 'DROGUE • • . • RELEASE • POINT :s ' • �:_�_' Oi, • '• • •' 15 • . O TO 2 KNOTS _ • • • ,� '� PREVAILING WINDS ' NORTHERLY. FIRST 3 • :;, :: MEASUREMENTS DROGUE CHECK TIMES SOUTHERLY. LAST 3 '• MEASUREMENTS • , •'' TIDE (feet) 12 . TIME •. �� '. • SOUNDINGS IN FEET Figure 10 DROGUE STUDY FLOOD TIDE AVERAGE TIDAL EXCHANGE } a :i w a0-D m a O 0 i. d 41 Id b a� O w 00 al b A a3 ca m 41 al R it d ■ O 41 O .Q b f: M-1 t) W to a W O i►s 0 a� Q d ri E 24 � 1 � Oo 00 Oo coo i o qcr o M c �I O 1 O N ar 1 1 I w I I �1 I CO O uj 0 t— to M Co 1 UA -1 C! U! C0 N O CD C7 I Cq M N M N M M N �-+ 1 0404 N N N N N N In 1 1 1 +� 1 W 1 v 1 I co co co co M T-4 M r-1 M V-+ M ri 1 w 1 A 1 1 O t- t0 M sob d d 44 41C V a o eu 0 24 indicate that horizontal dispersion was on the order of 104 cm2 /s which is relatively small but typical for bodies of water the size of Mats Mats Bay (Chapra and Reckow, 1983). The channel is vertically well mixed. Tidal inflow proceeds uniformly throughout the channel. Peak observed inflow rate during the average tidal exchange was 1.3 feet per second from the top to within 1 foot of the bottom. During outflow, peak flow was 1.4 feet per second two feet deep and dropped linearly to about 0.4 feet per second just above the bottom. Flow through the channel apparently moves as a plug. Available Light Light, rather than nutrients, controls the rate of phytoplankton growth for much of the year in Puget sound waters (Winter rd g_l 1975). Available light for phytoplankton photosynthesis depends upon the amount of incident solar radiation as well as water clarity. Average daily solar radiation (It) has been obtained from Astoria, Oregon (1953- 1968 average) and is considered to be more representative of Mats Mau Bay than data from Sea -Tac airport. These data show that light levels vary seasonably from a peak of about 526 ly /d in July to a minimum of 77 ly /d in December. Solar radiation is expressed in langleys per day (ly /d, a heat measurement of 1 gram calorie per square centimeter of surface). Strickland (1958) has demonstrated that about one half of It is available for phytoplankton growth: 1/2 It - Io This available light is further reduced by selective adsorption and scattering as it penetrates the water column. The reduction is described by Beer's Law, which can be rearranged to calculate the average light available for phytoplankton photosynthesis (I): I - (Io /kz)(1 —e-kz) where, z is the depth of the mixed larger and k is the light extinction coefficient. The light extinction coefficient is obtained from secchi depth: i k - 1.44 /secchi depth 25 Secchi depth, which is an indicator of water clarity, has been measured to range from 2.2 m to >5.1 m (Table 5). For other months of the year secchi depth has been conservatively estimated to be 3 m. Algal blooms potentially develop when the average available light in the water column (I) exceeds 40 ly /d. Ambient light levels have been calculated for the mid bay (Station 3) assuming that the mixed depth extends to the bottom. The results indicate that light is sufficient to support algal blooms between the months of March through September but that the winter months of October through February have shorter days and low sun angle and, thus, too little ambient light to support rapid phytoplankton growth. Oceanographic convention describes critical depth (Dr) as the depth where photosynthetic oxygen production in the water column is equal to the oxygen consumed by water column respiration. The light level at the critical depth is on the order of 5.0 ly /d and thus: Dcr - I6/(5.0)k The calculated critical depth in all portions of Mats Mats Bay ranged from 30 m to 161 m, always well in excess of the water depth, and thus water column oxygen production is expected to exceed oxygen utilization within the bay all year long. A conclusion is that oxygen depletion is not anticipated to occur even at depth in the water column. Oxygen demand of the sediments however is likely to periodically result in reduced oxygen levels near the sediment -water interface. Temperature Mats Mats Bay remained cool throughout the summer, 14.2 t 1.1 'C near the surface and 12.9 t 1.0 'C at depth, which is not significantly warmer than surface waters of Admiralty Inlet (Sta. 1). Significant temperature stratification did exist within Mats Mats Bay. Distinct thermoclines existed at depths of 8 and 9 feet during the July and August surveys, but temperatures were uniform from top to bottom in September and October. Water which entered and exited through the channel was the same temperature as Mau Mats Bay bottom water and was significantly cooler than water above the thermocline. This information indicates that water exchange involves water beneath the thermocline to a larger degree than water above the thermocline. It is interesting to note that the minimum temperature necessary for oyster spawning is 18 °C, considerably Table 5. Water quality indicators for Mats Katz Bay during the summer of 1989. Station, locations are as indicated on Figure 2. T and B refer to top and bottom and I and 0 to inflow and outflow samples, respectively. t STANDARDS > 2 > 7.0 14 < 10 or >(bkg -0.2' 27 NITRATE TOTAL TOTAL SOLUBLE . SECCHI DISSOLVED ♦ UJELDAHL PH09- PH09- FECAL PHAEO- DATE STA DEPTH TEMP SALINITY OXYGEN AMMONIA NITRITE NITROGEN PHORUS PHORUS COLIFORM CHL a PHYTIN ■ deg.0 ppt mg/L ug NA ug N/L ug NA ug P/L ug P /L.NPN /100m1 ug /L ug /L 11- Jun -89 IT 4.3 13.0 29.10 10.4 52 95 467 76 < 2 8.20 1.50 1B 11.8 30.00 8.4 58 143 208 75 < 2 2.30 0.40 10- Jul -89 2I > 3.2 10.8 30.43 10.2 28 159 256 61 44 < 2 7.00 < 0.10 20 > 3.8 13.0 30.38 11.9 69 67 346 53 40 2 3.90 0.20 3T 2.2 14.2 30.34 12.6 50 63 < 100 Be 38 11 5.50 1.30 3B 11.8 30.43 7.2 123 51 175 66 47 < 2 3.60 0.80 4 0.7 13.7 30.29 12.8 23 70 211 61 40 < 2 13.40 3.19 IT 5.8 11.9 29.82 10.1 55 140 < 100 63 < 2 3.50 < 0.10 1B 11.7 29.89 6.6 58 168 < 100 73 < 2 1.70 < 0.10 07- Aug -89 2I > 4.7 12.2 31.30 12 174 354 87 57 < 2 5.05 < 0.10 20 > 4.8 12.3 31.70 8.4 11 174 462 84 59 < 2 3.19 0.32 3T 3.0 15.3 31.12 11.6 < 10 47 286 74 32 < 2 11.87 0.59 3B 13.0 31.23 10.0 < 10 71 502 81 69 2 14.97 < 0.10 4 > 1.6 15.5 31.52 12.6 12 59 585 80 40 < 2 10.06 0.50 IT 8.8 14.5 30.69 9.9 46 160 584 78 49 4 6.30 < 0.10 1B 31.41 6.9 29 211 327 91 66 < 2 3.00 < 0.10 06- Sep -89 2I > 4.9 12.9 30.98 7.5 20 163 329 79 75 -< 2 5.48 < 0.10 20 > 4.8 15.8 30.69 9.8 23 194 < 100 79 78 :< 2 4.11 < 0.10 3T 3.7 14.9 30.65 9.0 13 168 256 81 72 5 7.40 < 0.10 3B 14.5 30.98 7.5 23 168 < 100 88 72 < 2 5.86 < 0.10 4 > 2.8 13.6 30.32 7.6 26 164 199 86 71 < 2 6.51 < 0.10 IT 7.6 17.0 31.23 7.5 25 154 < 100 83 79 < 2 6.00 < 0.10 18 13.0 31.16 5.0 35 183 < 100 83 84 < 2 5.00 < 0.10 07- Sep-89 2I1 > 4.8 13.0 30.54 9.5 23 195 284 81 77 < 2 4.04 0.67 2I2 > 5.0 13.0 30.29 9.9 24 194 < 100 82 76 < 2 7.26 < 0.10 201 > 4.7 13.2 30.87 9.6 17 214 148 81 76 < 2 2.95 < 0.10 202 > 4.7 13.8 30.32 10.1 27 201 < 100 79 78 `< 2 2.65 0.60 29- Sep-89 2I1 3.7 12.5 30.11 9.5 45 228 272 .93 57 < 2 1.74 < 0.10 2I2 > 5.1 12.5 30.93 9.3 70 506 216 145 57 < 2 2.00 0.10 201 > 5.1 12.3 31.49 9.7 88 132 445 77 53 6 2.19 0.11 202 > 3.5 12.6 30.50 11.0 71 119 173 93 56 4 3.24 < 0.10 05- Oct -89 2I 5.1 12.0 30.49 9.2 63 223 246 86 53 4 t 0.10 2.29 20 > 5.0 11.7 30.42 8.5 100 231 490 91 57 < 2 0.45 t 0.10 3T 4.3 12.5 30.49 8.0 99 209 325 90 47 2 0.43 0.17 3B 12.4 30.28 5.1 77 192 390 91 57 < 2 0.37 0.94 4 > 1.9 12.2 30.45 6.3 103 206 205 93 53 7 1.34 < 0.10 IT 7.9 12.5 29.82 7.0 67 178 557 77 55 < 2 0.80 0.30 1B 12.0 30.56 5.8 63 225 557 92 67 2 < 0.10 < 0.10 AVERAGE 2I 4.6 12.4 30.63 8.1 36 230 257 89 62 2 4.08 0.45 20 4.8 13.0 30.85 9.6 50 214 288 87 62 2 3.26 0.14 3T 3.3 14.2 30.65 10.3 43 122 242 76 47 4 6.30 0.54 3B 12.9 30.73 7.5 58 121 292 82 61 2 6.20 0.49 4 1.8 13.8 30.65 9.8 41 125 300 SO 51 3 7.83 0.97 IT 7.5 14.0 30.39 8.6 48 158 335 75 46 2 4.15 0.15 1B 9.2 30.76 6.3 46 197 271 85 54 2 2.45 0.10 t STANDARDS > 2 > 7.0 14 < 10 or >(bkg -0.2' 27 1 warmer than was achieved in Mau Mats Bay during the study period. Oysters may maintain a natural population if waters are warm enough to support spawning every 10 years or so. Introduction of oyster spat by man will also permit oyster rearing at the observed temperatures. Dissolved Oxvaen Dissolved oxygen (DO) concentrations within Mats Mats Bay were generally high, on average about 150% supersaturated and not significantly different from'Admiralty Inlet values. In October, however, DO in bottom water (Sta. 3B) was 5.1 mg/L and in the northern station (Sta. 4) was 6.3 mg /L, both less than the Class AA water quality standard of 7.0 mg /L. Dissolved oxygen was also low offshore, (Sta. 1); 7.0 mg /L in surface water and 5.8 mg/L at depth (Table 5). Fall upwelling is characteristic in Admiralty Inlet and results in depressed DO levels. Because offshore water represents the source of water to Mats Mats Bay, the upwelling is partially responsible for the low DO levels. Water quality standards account for this and when natural conditions, such as upwelling, cause DO to be depressed near or below 7.0 mg /L, then man caused activities may further degrade DO by 0.2 mg /L. However, in Mats Mats Bay the DO was as much as 1.9 mg /L less than the background. It is not possible to accurately predict the extent that man's activities reduced DO in Mats Mats Bay. Man's influence includes such sources as the respiration of herring stored in net pens and the increase in oxygen demand of sediments as a result of the introduction of organic materials to the bay. The respiration of herring is considered to be very similar to that of their Atlantic allies, the menhaden, at about 0.1% mg DO /g wet weight /h when relatively inactive and not feeding (Durbin et al 1981). Based on 2.7 million herring per year, 14 d holding time, 30 g per fish and the above oxygen consumption rate, the fish consume 300,000 mg DO /h or about 0.1% of the incoming DO. The oxygen demand of the herring operation is thus not perceived to be a problem for Mats Mats Bay. Nutrients The nutrients of most concern for Mats Mats Bay are nitrogen (N) and phosphorus (P), because, when given sufficient light, one of these elements may potentially limit the • growth rate of phytoplankton. The ratio of N:P in marine phytoplankton is generally on the order of 10:1. Water which contains a ratio less than 10:1 has a relative shortage of N and is said to be N limiting for phytoplankton growth. Mats Mats Bay waters 28 t consistently had TN:TP and soluable N:soluable P ratios of approximately 5:1 and 4:1, respectively, indicating that N, rather than P, was in shortest supply for phytoplankton growth. Ratios of N:P within Mats Mats Bay did not differ significantly from station to station or from those of Admiralty Inlet. Despite indications of N limitation, the absolute level of dissolved inorganic nitrogen (DIN, the sum of nitrate + ammonia; the primary forms available for phytoplankton uptake) remained high (Table 5). Even during August when peak phytoplankton concentrations were observed, concentrations of DIN remained in excess of 47 pg N /L. Eppley et al. (1969) has shown that many coastal phytoplankters may grow at nearly maximal growth rates when DIN exceeds 15 pg N /L. Thus, with available nitrogen always available in excess of demand, nutrient limitation by N or P is not thought to have occurred. The sources of nutrients to Mats Mats Bay may be evaluated by mass balance methods (Table 6). These data suggest that marine input of nutrients from water outside the bay is by far the most important source. Creek TN levels on average were the same as those flowing into the bay via the channel, 472 versus 480 pg N/L but creek TP values were a bit greater, 141 versus 89 pg P/L (Table 7). But because creek flow was about 1900 times less than tidal inflow, the mass contribution from the creeks is considered negligible. Absolute concentrations of nitrogen in the three creeks are considered to be moderately low. The flow weighted DIN was 239 pg N/L which can be contrasted to a median DIN of 687 pg N/L for 44 streams in the Seattle -King County region (Metro 1988). In contrast, TP was rather concentrated in the Mats Mats Bay creeks. The flow weighted TP concentration was 141 pg P/L about 2.4 times greater than the Seattle -King County median of 58 pg P/L (Metro 1988). A third possible source of nutrients during the study period, internal loading, can be evaluated with the mass balance approach. Internal loading, in this case, lumps together all non -point nutrient sources, and does not include inflow from the channel or the three creeks. Notably, these sources may include, sediment release, groundwater and septage input, boater activity and the herring net pen operation. Internal loading is found by difference of inflow to the bay minus outflow and thus is subject to large error. It is • stressed that these results are not statistically significant, yet do yield insight on estuarine processes. Two tentative conclusions may be drawn from results in Table 6. TP apparently sedimented during the summer, but at the onset of fall turnover in 29 1 QfO 1 O .0 woo -'VA: A: Y'f W 9 G! . s m 019 .o �. 1. 0!Nm0.*I! m a m Pf m l N I -mO�ANm 1 v 1 .t. �w�.:.'.neem . i m 1 O.. tOla(000 = 1�ir,Ob ODftIV esi.+omma�o 47 40-4 m� N! N ' -m w 1N 1� 1 !•r N .y 40111N1000 to i� l-oe 1�.•+b ON t NNAO toa b go WD mml0 r1 1 1 P.. aD 110 1 00 .-1 l a7 a Oa�.•lwt7mm Qm.+I IDOmN 1 l►a7 tr .r 10001 1 m 1 O.. tOla(000 PC a01D Ol O1Nm0 t'f Ol O1N W 10m V 1 ;a a!!!00 40111N1000 to i� l-oe 1�.•+b ON t NNAO toa b go WD mml0 r1 1 1 P.. aD 110 1 00 .-1 l a7 00 .r N Ps .4 t+If t 1 1 1 O 1 r+ N 111 a = 001 t7 m.e 0.0.0 Oat -l0.r t0 N.o mama7!!t► 1 m 00A.. .+t0 t7 t- t... tO t-! Ot-17 to to Noes! O.r .HAN W O! 40 491.40 1 1 0 1 tD Om so .+ O a t7 N .+ ;..O on l ae .� .+ l- "1 .. —r 1 0! 1 I 0 ra 94 pt M94 1 l.4 �.. it Oa�00+w1 -0! OWmO-w00 w CD ar a7 r't�.+m i r7 O aD ; MO-4 .4 t-O iD 1; 01 .0N 0; OO tON l� NN O/ t0 ..rA -w t- t! OO.r.H OI R! laam 0; C; w o la9m Nt�.. 14 !a"1as t- -d .-a 1 b I !■ < O.. 6094 aN b.ti ; 'I O ..+Vi 1 C a paaD 0.. 94100 Ct►0�49 .-.NO !l000 -.! I •�. m Oa al:a Ot0100vralm NaD0amt7a .1t °l.r CD "4 a VS CN«a 117 .0.o t- .. to P1 t►t0.P0 +• i7 1 o m aD t- V, a•. CM in a a N .�. 94 0 .•. in N 0, O i i a 1 ao l OD 94 vs �. .0 1 t .0 1 O t00000 t- .1 s .. = i a t0 i o 1 O 1 �. 1 lw co 10 ° + 11Oq tD 1 -4 S 4 •. co 0t- 1 �S. I o V W ■ i C + � O/ 1 m t�O1 f0 CD �'OOm mO Ot9.:0 P) �v �0 000000 OC O a s 10Nm94 Na040 Z O m 60..0940.. a M.4 a00000 ei 7 Id •t►. a+ ° �o �o tom to lea m �o lea "Om m wo Ao >b a ■ JC .11 .tl .IK it Ji ti m m it X .t1 ?i .M W w .t1 ii Jt .ii .Y JL O .°. .°. 0 w •�. p0p O L O • E p0 O C • M Y it p00 41r+ + 1. 6 0 + '� tl 0 i 0 u— O ..o.. p �• �. .NM 14, o g+a .0 -� ogw �= toto. r� t"/aoi +acg ea ozo +a 8 .O•iar 64w o ass � .i A O4M3r0+Oi0� g.0Y.. .4a40 t+i = �< Om9- 62+ W <V+ w 0 ., tti ► � o w tl: i M pO M M M 1 t a psp O O 0 0 0 O O t- O Ot 0 O d V-4 t� N to V4 to 9-1 Cn N N OC N to t- t- en N to to N t°e aaa t� a a oo ° ° at o on m co t- .n an V m oaa a 0 1 aE V3 a o o co co 9-4 N at er N to 94 a D \ N to o CD LO to C73 "r ar m .r v m :l] Cd R. r1 .-1 N .4 .4 .4 .4 .4 d a 'aS W a N 40 ri O -WtDcn tot- Up W-1 d a a n \ o to M w •a W-4 cr N on o m n m < A O Z N cntod' Nmr4 MN N N it d P. O to V H a Co .r to t` to m o 0 0 .d r E + H z .-t to .4 CO U') 1 to to .� .0 H H a0 V Z Z 7 -�4 a a tr 0 CD V-4 0 0 0 tee .r o 00 Z \ CA .4 1-4 N r4 .4 .-1 r-1 N C4 to Ll o z ri m z (W� W > Z cn tD Co N co !rJ N N r4 m IV a W a • v aoi� m o O � °OO BOO °' w U» o a o A W m U Co .r t'7 to •r W-4 er Co Co t- cn U U 2 a qw O CD CM to cn to to O Ct qr -r4 Fr �Q�..aa U eM N .4 r/ 1-1 V-1 .4 94 N V-i N • m r4 U O 41 O O U U ow RL U -r d' c7 N er O O to Co to m .0 b0 448 M to N 844 r4 t) E •-{ .-4 1-4 9.4 94 .4 .4 .4 .-1 rl .� M N N to O to 1-4 to t7 t— er 7.4 to w4 to Cl) O m N N t— 9-4 N M -W !N r4 N O r-1 .-+ O O r4 O O m 0 0 ih a o00 000 000 of ;o 0 }t Q r4 N th rt N VD r-t N m .4 N V) d E UUU UUU UUU U U U O Os Ot m t— W CO O; co C 0W W E .4 w a +� E n Go F ° o 0 o wia 31 � 'i - I October, net release to the water column occurred. Sediment during July and August consumed approximately 4% to I I% of the P which entered the Bay, and in October sediment P release contributed about 6% of the P load. This process is consistent with known mechanisms governing P solubility. When low or no oxygen is present, sediment iron is reduced to soluble ferrous (II) form with simultaneous release of P with which it had coprecipitated. However, with oxygen present, coprecipitation of iron and P occur. Measured water column DO was always sufficient to cause coprecipitation of iron and P, however, the inference is that anoxic conditions developed at and below the sediment surface throughout the study period and in October sediment P was mobilized into the water column by complete vertical mixing. TN was, on average, generated in the bay, but no consistent trends were observed. In summary, nutrients are in abundant supply in Mats Mats Bay and are not perceived to limit the growth of phytoplankton. Inflow of offshore water represents the single most important source of nutrients to Mats Mats Bay because of the large volume exchanged. Creek water may have moderately elevated P concentrations, but flow is so small that changes in bay nutrient concentration or ratios is not likely to alter phytoplankton growth or species composition. Bay sediments themselves may seasonally act to scavenge or release important levels of P. Phvtoolankton Abundance Quantification of water column chlorophyll g (chi lil is a frequently used indicator of phytoplankton abundance. As for total nutrients, chi g concentrations did not differ significantly between the offshore station and Mats Mats Bay stations. No established water quality standard exists for chi g but frequently used guideline suggests that chi a concentration in excess of 10 pg /L may constitute an aesthetic nuisance and possibly result in seriously depressed oxygen levels. In Mats Mats Bay, average chi g levels were 3.3 to 7.8 pg /L, but the 10 pg /L guideline was exceeded in 4 of 28 samples (14%), with a peak concentration of 14.97 pg /L. These concentrations are not considered alarming. Greater yet chi g concentrations were noted in nearby Port Ludlow during the same period (HLA 1989). However, high concentrations of chi g during 1984 and 1989 in Port Ludlow was not attributed to man's influences, but to natural variation in phytoplankton growth and death rates. 32 i These same influences, namely available light, zooplankton grazing and pycnocline development, may have been such to permit greater than normal chi It accumulation in Mats Mats Bay as well. Mass balance calculation (Table b) indicates that about 30% less chi a washed out of Mats Mats Bay than entered. Two theories, which are not mutually exclusive, may account for this. Either phytoplankton death exceeded growth because of zooplankton and oyster feeding or the phytoplankton were able to adjust their vertical placement in the water column to avoid washout. Paralytic shellfish poisoning may occur when toxic phytoplankton species are present, sometimes visible as red tides. Shellfish toxin levels are routinely monitored in Mats Mats Bay and at Olele and Klas rocks near the channel opening by DSHS. These results indicate that dangerous levels of toxin occasionally occur (DSHS 1988). Water Column Fe a] Coliform Bacteria Water column fecal coliform bacteria were not abundant in Mats Mats Bay (Table 5). The maximum detected concentration was 11 MPN/ 100 mi but 19 of 28 samples contained less than the detection limit of 2 MPN /100 mi. The geometric mean concentration was less than 2.5 MPN /100 ml, within the 14 MPN /100 ml geometric mean limit imposed on Class AA Waters (WAC 173 - 210 -045). Low fecal coliform levels in Mats Mats Bay have been confirmed by other studies. A suite of 13 samples collected during May through July 1987 (Harper -Owes, 1988) had a geometric mean concentration of 4 MPN /100 ml. Four stations sampled 12 to 14 times each by Rubida (1989) had geometric means which ranged from 0.4 to 2.0 MPN /100 ml. Despite low fecal coliform concentrations in bay water, the three creeks exceeded Class AA water quality standards. These standards, for Class AA freshwaters, state that fecal coliform organisms shall not exceed a geometric mean of 43 organisms /100 ml with not more than 10% of the samples in excess of 100 organisms /100 ml. Ten samples collected from the three creeks had a geometric mean of 121 MPN /100 ml and the estimated upper 10% was 920 MPN /100 ml. All three creeks exhibited violations of the standards. As contrast, 44 creeks in the Seattle -King County area displayed a geometric mean of 188 MPN /100 ml, also in violation of standards. Rubida (1989) measured fecal coliform in the same 3 creeks during 1988 and found substantially lower concentrations; of 24 33 samples collected, no violations of water quality standards were observed. Geometric means in 1988 were found to vary from 22.5 to 43.7 MPN 1100 ml. No significant changes in land use, boater pressure or increase in groundwater table are thought to have occurred between 1988 and 1989 and thus it is difficult to reconcile the great increase in fecal coliform data. However, because from a mass balance perspective the creeks represent a tremendous source of bacteria to the bay (Table 6) and because the creeks drain to shorelines from which oysters are harvested, the observed freshwater bacterial levels must be considered as a potential threat to human health. Shellfish Fecal Coliform Bacteria Oysters filter tremendous volumes of water each day and in so doing, concentrate available algae, bacteria and pathogenic microorganisms. Fecal coliform bacteria are among the organisms concentrated by oysters. Fecal coliform bacteria are not intrinsically hazardous to human health but are a sensitive indicator of fecal contamination. Thus, when.fecal coliform bacteria are detected, in water or oyster tissue, infectious disease microorganisms such as salmonella, typhoid or cholera may also be present if infected individuals are in the catchment. Freshwater input typically represents a large source of fecal contamination to marine systems and, because freshwater tends to float, highest contamination levels often exist at the 'surface. Because oysters reside in the intertidal zone, they are in an area of high exposure to surface waters. As discussed previously, bay water had essentially undetectable fecal coliform bacterial concentrations, but the three inflow creeks contained relatively high concentrations. The Food and Drug Administration has promulgated a guideline of 230 fecal coliform organisms per 100 ml of shellfish tissue 1, which applies to commercial sales. Oysters in Mats Mats Bay exceeded this guideline in 5 of 6 samples, having a geometric mean of 333 MPN /100 ml and a maximum of 673 MPN /100 ml (Table 8). Samples collected immediately adjacent to inflow creeks displayed greater concentrations of fecal coliform than did oysters from a location distant from the creeks; with geometric means of 552 versus 259 organisms/ 100 ml. Prior data (Jefferson County Department of Health, Pers. k Comm.) include a shellfish sample from June 1985 with 20 MPN /100 ml and three during 1987 which showed levels of 20, 78 and 1300 MPN /100 ml. Thus, fecal contamination of oysters is indicated, and likely via the inflow creeks. 34 OD O M 43 01 Rr 4J a d U a O U O 4.1 M rl O U ■ U 0) W d ' a 00 ■ M R. 0) 01 A O .Ae OD 00 ■ ao d a b E \V J ` 1 O go 1 N .� 1 N V4 4 i v U 1 O i 1 1 1 r;A tD t t� v 4-) j to 1 1 1 O P 1 co .. 1 N v � i 1 1 O 1 N cr) A I O 1 ►a 1 1 O 1 N ri 1 tD N A 1 a 1 ra 1 1 O 1 m � 1 ar .-. 1 N v rl 1 �'a 1 1 M ■ O O i� a a Rii sw ..4 .-1 U n-1 b U 1 co O I M M I M N I 1 O Cl 1 � •-1 I 1 d d a a 1 z z 1 � � 1 d b s U b M d I» i o a d cti 35 N d Rr d OQ ■ 0) w jy • � d 0 c.dd w r'I O O d R � � ■ a a A O O ■ ■ aS4 a d � � m d d O R Q ti d O � fr it ed O O is •• O C C ■ .0 it 14 ON d 01 .0 fJ 4J . M � � O 0) = Z CA .0 O +» iJ M 1w O i• 41 O O O 0zaoz w .. Q vvv U �t a i 4 4. No significant differences in water column temperature, dissolved oxygen, nutrients, chl I or fecal coliform bacteria were noted between Mats Mats Bay and Admiralty Inlet. This apparent uniformity is attributed to the high extent of water exchange. S. Fecal coliform levels were quite low in bay water, but were in excess of regulatory standards in creek water and in oyster tissue. 37 I J i' ti ( REFERENCES APHA. 1985. Standard methods for the examination of water and wastewater. 16th Ed. American Public Health Association. 1268 pp. Chapra, S. and K. Reckow. 1983. Engineering Approaches for Lake Management. Vol. 2: Mechanistic Modeling, Butterworth, Boston, 492pp. Collias, E.E., N. McGary, and C.A. Barnes. 1974. Atlas of physical and chemical properties of Puget Sound and its approaches. University of Washington Press. Washington Sea Grant Publication. 235pp. Determan, T.A., B.M. Carey, W.H.. Chamberlain and D.E. Norton. 1985. Sources affecting the sanitary conditions of water and shellfish in Minter Bay and Barley lagoon. WDOE Report No. 84 -10. 186 pp. DSHS. 1988. Red Tide Report 1985 -1987. Department of Social and Health Services, Shellfish Section. 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